<?xml version="1.0"?>
<ownershipDocument>

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    <periodOfReport>2025-11-05</periodOfReport>

    <notSubjectToSection16>1</notSubjectToSection16>

    <issuer>
        <issuerCik>0001441683</issuerCik>
        <issuerName>APPIAN CORP</issuerName>
        <issuerTradingSymbol>APPN</issuerTradingSymbol>
    </issuer>

    <reportingOwner>
        <reportingOwnerId>
            <rptOwnerCik>0001706796</rptOwnerCik>
            <rptOwnerName>Winters Christopher</rptOwnerName>
        </reportingOwnerId>
        <reportingOwnerAddress>
            <rptOwnerStreet1>C/O APPIAN CORPORATION</rptOwnerStreet1>
            <rptOwnerStreet2>7950 JONES BRANCH DRIVE</rptOwnerStreet2>
            <rptOwnerCity>MCLEAN</rptOwnerCity>
            <rptOwnerState>VA</rptOwnerState>
            <rptOwnerZipCode>22102</rptOwnerZipCode>
            <rptOwnerStateDescription></rptOwnerStateDescription>
        </reportingOwnerAddress>
        <reportingOwnerRelationship>
            <isDirector>0</isDirector>
            <isOfficer>1</isOfficer>
            <isTenPercentOwner>0</isTenPercentOwner>
            <isOther>0</isOther>
            <officerTitle>General Counsel</officerTitle>
        </reportingOwnerRelationship>
    </reportingOwner>

    <aff10b5One>0</aff10b5One>

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        <nonDerivativeTransaction>
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                <value>Class A Common Stock</value>
            </securityTitle>
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            </transactionDate>
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                <equitySwapInvolved>0</equitySwapInvolved>
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                </transactionShares>
                <transactionPricePerShare>
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                </transactionAcquiredDisposedCode>
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                </sharesOwnedFollowingTransaction>
            </postTransactionAmounts>
            <ownershipNature>
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                </directOrIndirectOwnership>
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        </derivativeTransaction>
        <derivativeTransaction>
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                    <value>1623</value>
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    <footnotes>
        <footnote id="F1">Each Restricted Stock Unit (&quot;RSU&quot;) converts into Class A Common Stock on a one-for-one basis.</footnote>
        <footnote id="F2">Each RSU represents a contingent right to receive one share of Issuer's Class A Common Stock (or its cash equivalent, at the discretion of the Issuer).</footnote>
        <footnote id="F3">The RSUs were granted on August 2, 2022, and vest in four (4) equal installments commencing on November 6, 2023, provided that the Reporting Person has provided continuous service to the Issuer through such vesting date.</footnote>
        <footnote id="F4">The RSUs were granted on October 31, 2023, and vest in four (4) equal installments commencing on November 5, 2024, provided that the Reporting Person has provided continuous service to the Issuer through such vesting date.</footnote>
        <footnote id="F5">The RSUs were granted on November 5, 2024, and vested on November 5, 2025.</footnote>
        <footnote id="F6">The RSUs were granted on November 5, 2024, and vest in four (4) equal annual installments commencing on November 5, 2025, provided that the Reporting Person has provided continuous service to the Issuer through such vesting date.</footnote>
    </footnotes>

    <remarks></remarks>

    <ownerSignature>
        <signatureName>/s/ Angela Patterson, Attorney-in-Fact</signatureName>
        <signatureDate>2025-11-06</signatureDate>
    </ownerSignature>
</ownershipDocument>
